Incident and in situ irradiance in Lakes Cadagno and Lucerne: A comparison of methods and models     

Patrick J. Neale  Peter Bossard  Yannick Huot  Ruben Sommaruga 《Aquatic Sciences - Research Across Boundaries》2001,63(3):250-264

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Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy     

Fossi MC  Marsili L  Lauriano G  Fortuna C  Canese S  Ancora S  Leonzio C  Romeo T  Merino R  Abad E  Jiménez B 《Marine environmental research》2004,58(2-5):269-274

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily - Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.  相似文献   

Spring distribution of dissolved organic matter in a system encompassing the Northeast Water Polynya: Implications for early-season sources and sinks     

Annelie Skoog  Margareta Wedborg  Ruben Lara  Gerhard Kattner 《Marine Chemistry》2005,94(1-4):175

This study addresses sources and diagenetic state of early-season dissolved organic matter (DOM) in the Northeast Water Polynya (NEWP) area northeast of Greenland from distributions of humic substance fluorescence (HSfl), dissolved organic carbon (DOC), and dissolved organic nitrogen (DON) in the water column inside and outside the NEWP area. The water masses of the polynya area had acquired their spring/summer temperature–salinity characteristics at the time of sampling, and also had individual, different DOM signatures. DOC concentrations were variable within and among water masses in the polynya area, indicating patchy local sources and sinks of DOC. PySW and polynya intermediate water (PyIW) had higher average DON concentrations and average lower C:N ratios than polynya bottom water (PyBW), indicating a larger fraction of fresh DOM in PySW and PyIW than in PyBW. Ice-covered, polynya area surface waters (PySW) had higher DOC concentrations (113±14 μM, n=68) than surface water (SW) outside the polynya area (96±18 μM, n=6). The DOM C:N ratios in a low-salinity, ice-melt subgroup of PySW samples indicate labile material, and these low-salinity surface waters appeared to have a local DOC and DON source. In contrast, HSfl was significantly lower inside than outside the NEWP area. Despite the lower HSfl values within the NEWP area, the PySW values were high when compared to open-ocean water. There were no local terrestrial sources for HSfl to the NEWP area and the East Greenland Current is therefore proposed as a likely source of allochtonous HSfl. When HSfl was used as a conservative tracer, up to 70% of the water in PySW and PyIW was found to be derived from SW, which contains a high fraction of water from the East Greenland Current. Similarly, a mixing model based on HSfl indicated that 80% of early-season DOC and 90–100% of early-season DON in PySW and PyIW were derived from SW, indicating a potentially high fraction of terrestrially-derived, relatively refractory DOM in the early-season NEWP area.  相似文献   

Characterization of dissolved organic matter in anoxic rock extracts and in situ pore water of the Opalinus Clay     

Amandine Courdouan  Iso Christl  Sbastien Meylan  Paul Wersin  Ruben Kretzschmar 《Applied Geochemistry》2007,22(12):2926

Dissolved organic matter (DOM) from the Opalinus Clay, a potential host rock for the disposal of radioactive waste, was isolated under strictly anoxic conditions from ground rock material and compared with DOM of in situ pore water samples. For the extractions, deionized water, synthetic pore water (SPW, water containing all major ions at pore water concentrations but no organic matter) and 0.1 M NaOH were used. The influence of the solid-to-liquid ratio, extraction time, acid-pretreatment and O₂ exposure of the rock material on the isolated DOM were investigated. Liquid chromatography coupled with a total organic C detector (LC-OCD) and reverse-phase ion chromatography were used to characterize the DOM size distributions and to determine the low molecular weight organic acid (LMWOA) contents in the pore water samples and the rock extracts.The results revealed that only a small portion of the total organic C of the rock material (<0.38%) was extractable, even after removal of carbonates by acid-pretreatment. The concentrations of dissolved organic C (DOC) were found to range from 3.9 ± 0.4 to 8.0 ± 0.8 mg/L in the anoxic extracts. The pore waters exhibited similar DOC concentrations ranging from 1.2 to 15.8 ± 0.5 mg/L. The analysis by LC-OCD showed that the DOM extracted under anoxic conditions and the pore water DOM mainly consisted of hydrophilic compounds of less than 500 Da. The DOM extracted with SPW was most similar in size to the pore water DOM. Grinding the rock under oxic conditions increased the DOC yields and shifted the size distribution toward higher molecular weight compounds compared to the strictly anoxic treatment. Acetate, lactate and formate were identified in all extracts and in the pore water. In total, LMWOA accounted for 36% of the total DOC in both pore water and SPW extracts. The results imply that controlled anoxic conditions and the use of SPW as an extractant are required to isolate DOM from Opalinus Clay rocks which most resembles the in situ pore water DOM with respect to its size distribution and the LMWOA contents.  相似文献   

A locally conservative variational multiscale method for the simulation of porous media flow with multiscale source terms     

Ruben Juanes  Francois-Xavier Dub 《Computational Geosciences》2008,12(3):273-295

We present a variational multiscale mixed finite element method for the solution of Darcy flow in porous media, in which both the permeability field and the source term display a multiscale character. The formulation is based on a multiscale split of the solution into coarse and subgrid scales. This decomposition is invoked in a variational setting that leads to a rigorous definition of a (global) coarse problem and a set of (local) subgrid problems. One of the key issues for the success of the method is the proper definition of the boundary conditions for the localization of the subgrid problems. We identify a weak compatibility condition that allows for subgrid communication across element interfaces, a feature that turns out to be essential for obtaining high-quality solutions. We also remove the singularities due to concentrated sources from the coarse-scale problem by introducing additional multiscale basis functions, based on a decomposition of fine-scale source terms into coarse and deviatoric components. The method is locally conservative and employs a low-order approximation of pressure and velocity at both scales. We illustrate the performance of the method on several synthetic cases and conclude that the method is able to capture the global and local flow patterns accurately.  相似文献   

Isolation and characterization of dissolved organic matter from the Callovo–Oxfordian formation     

Amandine Courdouan  Iso Christl  Sébastien Meylan  Paul Wersin  Ruben Kretzschmar 《Applied Geochemistry》2007

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Origins and genesis of loess deposits in central Spain,as indicated by heavy mineral compositions and grain‐size variability     

Daniel Wolf  Karoline Ryborz  Thomas Kolb  Ruben Calvo Zapata  Jesús Sanchez Vizcaino  Ludwig Zller  Dominik Faust 《Sedimentology》2019,66(3):1139-1161

The formation of loess deposits strongly depends on the availability of deflatable dust‐sized material. Identification of source areas and mechanisms of dust production is essential for an appropriate characterization of related palaeoenvironmental conditions. So far, little research has been done on loess deposits in the Mediterranean region and information about mechanisms of dust production is very rare. In this context, it is not clear from where the loess deposits from the upper Tagus Basin in central Spain originated. The main objective of this study was to find out whether these loess deposits were formed primarily by mountain processes and fluvial comminution, or whether they have their origin in the weathering of Tertiary marls in the centre of the Madrid Basin. A further concern was to link the determined source areas with loess formation mechanisms and concomitant environmental contexts. Following a comprehensive approach using heavy minerals and grain‐size data, together with information on stratigraphic features and geomorphic positions, different local loess sources could be identified. This study shows that during the last 35 kyr a major proportion of the Tagus loess deposits was deflated from river floodplains, while the mountain region of the Iberian Range was identified as a significant source of respective floodplain sediments. Based on heavy mineral compositions and dating results, it was found that during Heinrich Stadial 3, sediment supply from the Iberian Range strongly increased, suggesting an environmental shift from initially warmer towards colder temperatures in late Marine Isotope Stage 3. Furthermore, it was found that grain‐size patterns clearly indicate maximum wind strengths during Heinrich Stadial 3, followed by Heinrich Stadial 2 and Heinrich Stadial 1. These results demonstrate that the formation of dust‐sized particles in this part of the Mediterranean operated similar to many other places in temperate and continental regions, and that weathering processes linked to hot and dry environments were only of minor importance.  相似文献   

Paleomagnetism of early cretaceous arapey formation (Northern Uruguay)     

Miguel Cervantes Solano  Avto Goguitchaichvili  Leda Sánchez Bettucci  Ruben Cejudo Ruiz  Manuel Calvo-Rathert  Vicente Carlos Ruiz-Martinez  Ruth Soto  Luis M. Alva-Valdivia 《Studia Geophysica et Geodaetica》2010,54(4):533-546

We report detailed rock-magnetic and paleomagnetic directional data from 35 lava flows (302 standard paleomagnetic cores) sampled in the Central-Northern region of Uruguay in order to contribute to the study of the paleosecular variation of the Earth’s magnetic field during early Cretaceous and to obtain precise Cretaceous paleomagnetic pole positions for stable South America. The average unit direction is rather precisely determined from 29 out of 35 sites. All A₉₅ confidence angles are less than 8°, which points to small within-site dispersion and high directional stability. Normal polarity magnetizations are revealed for 19 sites and 10 are reversely magnetized. Two other sites yield well defined intermediate polarities. The mean direction, supported by a positive reversal test is in reasonably good agreement with the expected paleodirection for Early Cretaceous stable South America and in disagreement with a 10° clockwise rotation found in the previous studies. On the other hand, paleomagnetic poles are significantly different from the pole position suggested by hotspot reconstructions, which may be due to true polar wander or the hotspot motion. Our data suggest a different style of secular variation during (and just before) the Cretaceous Normal Superchron and the last 5 Ma, supporting a link between paleosecular variation and reversal frequency.  相似文献   

Magnetic and pedological characterisation of a paleosol under aridic conditions in Spain     

Francisco Bautista  Maria Felicidad Bógalo  Antonio Sánchez Navarro  Avto Goguitchaichvili  María José Delgado Iniesta  Ruben Cejudo  Purificación Marín Sanleandro  Juana María Gil  Elvira Díaz-Pereira 《Studia Geophysica et Geodaetica》2018,62(1):139-166

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Geostatistical seismic inversion for non‐stationary patterns using direct sequential simulation and co‐simulation          下载免费PDF全文

Hamid Sabeti  Ali Moradzadeh  Faramarz Doulati Ardejani  Leonardo Azevedo  Amilcar Soares  Pedro Pereira  Ruben Nunes 《Geophysical Prospecting》2017,65(Z1):25-48

Geostatistical seismic inversion methods are routinely used in reservoir characterisation studies because of their potential to infer the spatial distribution of the petro‐elastic properties of interest (e.g., density, elastic, and acoustic impedance) along with the associated spatial uncertainty. Within the geostatistical seismic inversion framework, the retrieved inverse elastic models are conditioned by a global probability distribution function and a global spatial continuity model as estimated from the available well‐log data for the entire inversion grid. However, the spatial distribution of the real subsurface elastic properties is complex, heterogeneous, and, in many cases, non‐stationary since they directly depend on the subsurface geology, i.e., the spatial distribution of the facies of interest. In these complex geological settings, the application of a single distribution function and a spatial continuity model is not enough to properly model the natural variability of the elastic properties of interest. In this study, we propose a three‐dimensional geostatistical inversion technique that is able to incorporate the reservoir's heterogeneities. This method uses a traditional geostatistical seismic inversion conditioned by local multi‐distribution functions and spatial continuity models under non‐stationary conditions. The procedure of the proposed methodology is based on a zonation criterion along the vertical direction of the reservoir grid. Each zone can be defined by conventional seismic interpretation, with the identification of the main seismic units and significant variations of seismic amplitudes. The proposed method was applied to a highly non‐stationary synthetic seismic dataset with different levels of noise. The results of this work clearly show the advantages of the proposed method against conventional geostatistical seismic inversion procedures. It is important to highlight the impact of this technique in terms of higher convergence between real and inverted reflection seismic data and the more realistic approximation towards the real subsurface geology comparing with traditional techniques.  相似文献